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An organic compound is any member of a large class of chemical compounds whose molecules contain carbon. For historical reasons discussed below, a few types of compounds such as carbonates, simple oxides of carbon and cyanides, as well as the allotropes of carbon, are considered inorganic. The division between "organic" and "inorganic" carbon compounds while "useful in organizing the vast subject of chemistry...is somewhat arbitrary"^[1].

Organic chemistry is the science concerned with all aspects of organic compounds. Organic synthesis is the methodology of their preparation.

Contents 1 History 2 Classification 2.1 Natural compounds 2.2 Synthetic compounds 3 Nomenclature 4 Databases 5 Structure determination 6 See also 7 References

History

The name "organic" is historical, dating back to the 19th century, when it was believed that organic compounds could only be synthesized in living organisms through vis vitalis - the "life-force". The theory that organic compounds were fundamentally different from those that were "inorganic", that is, not synthesized through a life-force, was disproved with the synthesis of urea, an "organic" compound by definition of its known occurrence only in the urine of living organisms, from potassium cyanate and ammonium sulfate by Friedrich Wöhler in the Wöhler synthesis. The kinds of carbon compounds that are still traditionally considered inorganic are those that were considered inorganic before Wöhler's time; that is, those which came from "inorganic" (i.e., lifeless) sources such as minerals.^[1]

Classification

See Organic chemistry#Classification of organic substances

Organic compounds may contain atoms of further elements, so-called heteroatoms. Organometallic compounds constitute a further subsection, characterized by covalent bonds between organic carbon and a metal.

There is also a large number of inorganic carbon compounds to distinguish from organic compounds.

Natural compounds

An important subset of organic compounds is still extracted from natural sources because they would be far too expensive to be produced artificially. Examples include most sugars, some alkaloids and terpenoids, certain nutrients such as vitamin B₁₂, and in general, those natural products with large or stereoisometrically complicated molecules which are present in reasonable concentrations in living organisms.

Further compounds of prime importance in biochemistry are antigens, carbohydrates, enzymes, hormones, lipids and fatty acids, neurotransmitters, nucleic acids, proteins, peptides and amino acids, vitamins and fats and oils.

Synthetic compounds

Many polymers, including all plastics are organic compounds.

Nomenclature

The IUPAC nomenclature of organic compounds slightly differs from the CAS nomenclature.

Databases

• The CAS database is the most comprehensive repository for data on organic compounds. The search tool SciFinder is offered .

• The Beilstein database contains information on 9.8 million substances, covers the scientific literature from 1771 to the present, and is today accessible via CrossFire. Structures and a large diversity of physical and chemical properties is available for each substance, with reference to original literature.

• PubChem contains 18.4 million entries on compounds and especially covers the field of medicinal chemistry.

There is a great number of more specialized databases for diverse branches of organic chemistry.

Structure determination

See Structure determination

Today, the main tools are proton and carbon-13 NMR spectroscopy and X-ray crystallography.

See also

• Organometallic compounds
• Inorganic carbon compounds
• List of organic compounds | List of chemical compounds
• Inorganic compounds

References

1. ^ ^{a b} Spencer L. Seager, Michael R. Slabaugh. Chemistry for Today: general, organic, and biochemistry. Thomson Brooks/Cole, 2004, p. 342. ISBN 053439969X

v • d • e Concepts in organic chemistry Aromaticity, Covalent bonding, Functional groups, Nomenclature, Organic compounds, Organic reactions, Organic synthesis, Publications, Spectroscopy, Stereochemistry, List of organic compounds

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• This page was last modified on 13 October 2008, at 00:04.

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