This MedLibrary.org supplementary page on Polyimide is provided directly from the open source Wikipedia as a service to our readers. Please see the note below on authorship of this content, as well as the Wikipedia usage guidelines. To search for other content from our encyclopedia supplement, please use the form below:
Related Sponsors
| Polyimide | |
|---|---|
 |
|
| Density | 1430 kg/m3 |
| Young's modulus(E) | 3200 MPa |
| Tensile strength(t) | 75-90 MPa |
| Elongation @ break | 4-8% |
| notch test | 4-8 kJ/m |
| Glass temperature | >400 °C |
| melting point | none |
| Vicat B | 220(?) °C1 |
| Thermal conductivity (k) | 0.52 W/m.K |
| linear expansion coefficient () | 5.5 10-5 /K |
| Specific heat (c) | 1.15 kJ/kg.K |
| Water absorption (ASTM) | 0.32 |
| Dielectric constant (Dk) at 1MHz | 3.5 |
Polyimide (sometimes abbreviated PI) is a polymer of imide monomers. The structure of imide is as shown.
Thermosetting polyimides are commercially available as uncured resins, stock shapes, thin sheets, laminates and machines parts. Thermoplastic polyimides are very often called pseudothermoplastic. There are two general types of polyimides. One type, so-called linear polyimides, are made by combining imides into long chains. Aromatic heterocyclic polyimides are the other usual kind, where R′ and R″ are two carbon atoms of an aromatic ring. Examples of polyimide films include Apical, Kapton, Norton TH and Kaptrex. Polyimide parts and shapes include Meldin, Vespel and Plavis. Polyimides have been in mass production since 1955.
Contents |
Properties
Thermosetting polyimides are known for thermal stability, good chemical resistance, excellent mechanical properties, and characteristic orange/yellow color. Polyimides compounded with graphite or glass fiber reinforements have flexural strengths of up to 50,000 p.s.i. and flexural moduli of 3 million p.s.i. Thermoset polyimides exhibit very low creep and high tensile strength. These properties are maintained during continuous use to temperatures of 450°F (232°C) and for short excursions, as high as 900°F (482°C). Molded polyimide parts and laminates have very good heat resistance. Normal operating temperatures for such parts and laminates range from cryogenic to those exceeding 500°F (260°C). Polyimides are also inherently resistant to flame combustion and do not usually need to be mixed with flame retardants. Most carry a UL rating of VTM-0. Polyimide laminates have a flexural strength half life at 480°F (249°C) of 400 hours.
Typical polyimide parts are not affected by commonly used solvents and oils — including hydrocarbons, esters, ethers, alcohols and freons. They also resist weak acids but are not recommended for use in environments that contains alkalis or inorganic acids. Some polyimides, such as CP1 and CORIN XLS, are solvent-soluble and exhibit high optical clarity. The solubility properties lend them towards spray and low temperature cure applications.
Application
Polyimide is often used in the electronics industry for flexible cables, as an insulating film on magnet wire and for medical tubing. For example, in a laptop computer, the cable that connects the main logic board to the display (which must flex every time the laptop is opened or closed) is often a polyimide base with copper conductors. The semiconductor industry uses polyimide as a high-temperature adhesive; it is also used as a mechanical stress buffer. Some polyimide can be used like a photoresist; both "positive" and "negative" types of photoresist-like polyimide exist in the market.
References
- Modern Plastic Mid-October Encyclopedia Issue, Polyimide, thermoset, page 146.
Notes
- ^ Deformation temperature at 10kN needle load, source: A.K. vam der Vegt & L.E. Govaert, Polymeren,van keten tot kunststof, ISBN 90-407-2388-5
See also
|
|||||
 |
This article about polymer science is a stub. You can help Wikipedia by expanding it. |
Wikipedia content modification information:
- This page was last modified on 22 October 2008, at 13:30.
Wikipedia Authorship and Review
Wikipedia content provided here is not reviewed directly by MedLibrary.org. Wikipedia content is authored by an open community of volunteers and is not produced by or in any way affiliated with MedLibrary.org.
Wikipedia Usage Guidelines
This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article on "Polyimide".
The URL for this specific entry is:
All Wikipedia text is available under the terms of the GNU Free Documentation License. (See Copyrights for details). Wikipedia® is a registered trademark of the Wikimedia Foundation, Inc.