Siegbahn notation

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The Siegbahn notation is used in X-ray spectroscopy to name the spectral lines that are characteristic to elements. It was created by Manne Siegbahn.

The characteristic lines in X-ray emission spectra correspond to electronic transitions where an electron jumps down to an unfilled level in one of the inner shells of an atom. Such a hole in en inner shell may have been produced by bombardment with electrons in an X-ray tube, by other particles as in PIXE, by other X-rays in X-ray fluorescence or by radioactive decay of the atom's nucleus.

The table below show the correspondence between the name of a few lines and the electronic levels.

Siegbahn notation
Low energy level High energy level Name of the line
K (1s) L3 (2p3/2) 1
L2 (2p1/2) 2
M3 (3p3/2) 1
L3 (2p3/2) M5 (3d5/2) 1
L2 (2p1/2) M4 (3d3/2) 1
M5 (3d5/2) N7 (5p3/2) 1

This notation is widely used in spectroscopy, but the IUPAC (International union of pure and applied chemistry) recommends another notation.

Correspondence between the IUPAC Siegbahn notations
Siegbahn notation IUPAC notation
1 K-L3
2 K-L2
1 K-M3
1 L3-M5
1 L2-M4
1 M5-N7

References

See also

Wikipedia content modification information:

  • This page was last modified on 23 June 2008, at 09:01.

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