Sinalbin

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Sinalbin
IUPAC name [ [2-(4-Hydroxyphenyl)-1-[ [(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)-2-tetrahydropyranyl]thio]ethylidene]amino] sulfate
Identifiers
CAS number 20196-67-2
PubChem 656567
SMILES
Properties
Molecular formula C14H18NO10S2-
Molar mass 424.42342
Except where noted otherwise, data are given for
materials in their standard state
(at 25 °C, 100 kPa)

Infobox references

Sinalbin is a glucosinolate found in the seeds of white mustard, Sinapis alba. In contrast to mustard from black mustard (Brassica nigra) seeds, containing sinigrin), mustard from white mustard seeds has only a weakly pungent taste.1

The less sharp taste is due to the fact that the mustard oil from this specific glucosinolate, 4-hydroxybenzyl isothiocyanate, is unstable. With a half life of one or a few hours, the pungent mustard oil degrades to 4-hydroxybenzyl alcohol and thiocyanate ion, which are not pungent. Glucobrassicin is a structurally related glucosinolate that likewise yields a non-pungent isothiocyanate due to reaction with water.

Chemical name of sinalbin is p-Hydroxybenzylglucosinolate and cas number: 19253-84-0.

References

  1. ^ (French) RICHARD H. Arômes alimentaires Document de cours

Wikipedia content modification information:

  • This page was last modified on 12 September 2008, at 04:40.

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