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In a molecule, strain energy is released when the constituent atoms are allowed to rearrange themselves in a chemical reaction or a change of chemical conformation in a way that:

• angle strain,
• torsional strain,
• ring strain and/or steric strain,
• Allylic strain, and
• pentane interference

are reduced ¹. The external work done on an elastic member in causing it to distort from its unstressed state is transformed into strain energy which is a form of potential energy. The strain energy in the form of elastic deformation is mostly recoverable in the form of mechanical work.

For example, the heat of combustion of cyclopropane (696 kJ/mol) is higher than that of propane (657 kJ/mol) per methylene unit. Compounds with unusually large strain energy include tetrahedranes, propellanes, cubanes, fenestranes and cyclophanes.

References

1. ^ March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure Michael B. Smith, Jerry March Wiley-Interscience, 5th edition, 2001, ISBN 0-471-58589-0

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• This page was last modified on 18 November 2008, at 05:34.

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